Hydrazine is unstable and is usually handled as an aqueous solution for safety reasons. Chemical waste generators must also consult local, regional, and. Hydrazine hydrate is a colourless liquid highly soluble in water. Case study the problem 5 temporary mws and 9 permanent mws hydrazine by d857 jan 20 detections of 3 to 11 gl results do not agree with csm mw locations are upgradient and crossgradient of former hydrazine rack.
Show this safety data sheet to the doctor in attendance. In the case of contact with eyes, rinse immediately with plenty of water and seek. Hydrazines are highly reactive and easily catch fire. Anhydrous hydrazine ah technical data sheet 6 kb pdf ez drum system technical data sheet 186 kb pdf h70 propellant technical data sheet 129 kb pdf. The time for eliminating half of the oral dose was hydrazine hydrate 100% 64% hydrazine hydrazine hydrate 55% 35% hydrazine chemical name. Hydrazine is the simplest diamine mainly used as a reducing agent. Property hydrazine hydrazine sulfate molecular weight 32. Hydrazine sulfate is soluble in water but practically insoluble in ethanol. Hydrazine is highly toxic and dangerously unstable unless handled in solution as e. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 4. The level of harm depends upon the dose, duration, and work being done.
Hydrazine hydrate is a clear and colorless liquid at ambient. In the case of contact with eyes, rinse immediately with plenty of water and seek medical. This material does not contain any class 1 ozone depletors. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n. Hydrazine hydrate h6n2o cid 24654 structure, chemical names, physical. If inhaled if breathed in, move person into fresh air.
Hydrazine and udmh are listed as probable human carcinogens and classified under group b2 by the. With locations across canada, cleartech delivers quality chemicals and equipment from the top suppliers that you know and trust with the technical advice you need. Hydrazine is the simplest diamine 6 mainly used as a reducing agent. As a waterbased solution, hydrazine hydrate and its derivatives are supplied by arkema to be widely used as reducing agent, blowing agent, corrosion inhibitor, oxygen scavenger or intermediate of synthesis. Dermal contact may result in irritation or severe burns. Ac411745000, ac611195000, bp1200100, o3106500 synonyms. Hydrazine anhydrous,monomethyl hydrazinemmh,unsdimethyl. Hydrazine is an inorganic compound with the chemical formula n 2 h 4. Hydrazine hydrate 100% is toxic if swallowed and may cause digestive tract burns, central nervous system effects and methemoglobinemia, a condition that reduces the oxygen carrying capacity of the blood. Dilute hydrazine hydrate with water so the concentration of hydrazine is less than 5% ww. Hydrazine anhydrous has shown a high tumorgenerating pote ntial. Acute exposure to hydrazine may require decontamination and life support for the victims. For hydrazine determination in boiler waters by the pdimethylaminobenzaldehyde method. This material does not contain any hazardous air pollutants.
Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone. Properties safety and handling msds nmr spectrum synthesis route precursor and product computational chemical data. The revised idlh for hydrazine is 50 ppm based on acute inhalation toxicity data in animals comstock et al. Halogenated hydrocarbon, metals, acids, acid chlorides, hydrazine, dimethyl sulfate, inorganic acid chlorides. Chemtrec 8004249300 outside usa 7035273887 1216 6th ave n kent wa 98032 phone. Neutralize spilled hydrazine by diluting with water to a 5% or less solution. Accidental release measures personal precautions ensure adequate ventilation. Hydrazine, propellants, and han products online request only. Safety data sheet northwest missouri state university. Download fulltext pdf aqueous hydrazine as a promising candidate for capturing carbon dioxide article pdf available in international journal of greenhouse gas control 29. Hydrazine hydrate, 100% hydrazine, 64%, acros organics 100g.
It has a role as a carcinogenic agent, a teratogenic agent and a fuel. It is a simple pnictogen hydride, and is a colorless and flammable liquid with an ammonialike odor. Our product found applications in various industrial sectors such as water treatment, polymerization, agrochemicals, and pharmaceuticals. Hydrazine h2nnh2 or h2nnh2 or n2h4 or h4n2 cid 9321 structure, chemical. Symptoms of acute shortterm exposure to high levels of hydrazine may include irritation of the eyes. Hydrazine sulfate revision date 26feb2018 mobility will likely be mobile in the environment due to its water solubility. Hydrazine hydrate has been used for the deproteination of the enamel samples in a study.
Identification of the substancemixture and of the companyundertaking 1. Physical and chemical properties of hydrazine and hydrazine sulfate are listed in the following table. Material safety data sheet hydrazine sulphate msds section 1. After neutralization, transfer material to appropriate dot container for proper disposal. Material safety data sheet pharmaceutical chemistry. Along with graphite for the conversion of nitro compounds. Hydrazine safety and handling technical data sheet 73. Hydrazine hydrate, 80% hydrazine, 51% revision date 11jul2019 nfpa 6.
Cleartech is a canadian leader in the distribution of chemicals and chemical equipment for municipal, commercial and industrial uses. Hydrazine hydrate, reagent grade, n2h4 5060 % nh2nh2. It is a simple pnictogen hydride, and is a colorless and flammable liquid with an ammonialike odor hydrazine is highly toxic and dangerously unstable unless handled in solution as e. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. Anhydrous hydrazine ah monomethyl hydrazine mmh uns dimethyl hydrazine udmh hydrogen peroxideh 2 o 2 dinitrogen tetroxiden 2 o 4 hydroxylterminated polybutadienehtpb ammonium perchlorate ap e thylamine 1anhydrous hydrazine. In case of skin contact take off contaminated clothing and shoes immediately. Chemical product and company identification product name. Transformation of monosubstituted nitrobenzene derivatives to the corresponding anilines. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. After 96 hours, the concentration of hydrazine in guppies was about 144 ugg.
The hydrazine fuels handbook is a compilation of engineering information on the physical and chemical properties, storage and handling, production, transportation, safety, and the thermal and catalytic decomposition of the hydrazine family of fuels and their blends. Phenylhydrazine cas 100630 gr for analysis find msds or sds, a coa, data sheets and more information. These values give a bioconcentration factor of 316. Exposure to hydrazines can cause central nervous system effects as well as kidney and liver damage. Firstaid measures general advice show this safety data sheet to the doctor in attendance.
Hydrazine and hydrazine sulfate may be released to the environment through production, use, and waste disposal atsdr 1997, hsdb 2009. Used as a rocket propellant and raw material of herbicide and pesticide. Hydrazine and hydrazine sulfate national toxicology program. Niosh recommends as part of its carcinogen policy that the most protective respirators be worn for hydrazine at concentrations above 0. Hydrazine hydrate 80% extra pure msds cas 10217524 msds. Hydrazine is toxic to the liver, ruptures red blood cells, and may cause kidney damage. Add an equal volume of 5% calcium hypochlorite aqueous solution. Sigmaaldrich offers a number of hydrazine solution products.
Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. The time for eliminating half of the oral dose was 100 ml. Nfpa ratings scale 0 4 2 0 health 2 2 0 fire 0 reactivity 0. Aqueous hydrazine solution diamide hydrate cas number.
The hydrate may be produced commercially by three methods. Methylhydrazine in the digestive tract could be totally eliminated. The raschig process, the original commercial production process for hydrazine. It may be used as a reducing agent in the following. Ac19670, ac196710050, ac19671, ac196715000 synonyms. Pdf aqueous hydrazine as a promising candidate for. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Hydrazine 302012 hazard summary individuals may be exposed to hydrazine in the workplace or to small amounts in tobacco smoke. The principal current use for hydrazine is as an intermediate in the production of agricultural chemicals such as maleic hydrazide. It is also used as an intermediate in the manufacture of chemical blowing agents which are used in the. Hydrazine hydrate, 100% hydrazine, 64%, acros organics. The most complete free material safety data sheet msds list of. Neutralise using either msds no country specific data no oel data section 1.
Hydrazine occurs as a colorless, oily, flammable liquid that is miscible with water. Identification of the substancemixture and of the companyundertaking. Disposal considerations waste disposal methods chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Bp amoco, bp gas, power and ngl view, print and download the data sheets by simply entering the full. Hydrazine undergoes dehydrogenation in the presence of bimetallic nirh nanoparticles nps supported on nitrogendoped porous carbon npc derived from metalorganic frameworks zif8 to afford hydrogen. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. Monomethyl hydrazine mmh technical data sheet 92 kb pdf. Epas toxics release inventory reported that in 2007, environmental releases of hydrazine from 23 facilities totaled 16,759 lb, 14,570 lb of which was released by one facility to under. Page 25 safety data sheet sds phenylhydrazine classification system.
We ask that users who download significant portions of the database cite the hmdb paper in. Hydrazine solutions terminology technical data sheet 92 kb pdf. Hydrazine hydrate 55% may produce toxic effects similar to those described above, but with skin. Neutralise using either 99%,which is subject to the reporting requirements of section 3 of sara title iii and 40 cfr part 373. However, we make no warranty of merchantibility or any other warranty, express or implied, with. Material safety data sheets from the manufacturer or distributor.
1118 1244 753 1314 876 1195 1373 1173 1239 311 1444 868 457 1301 404 1463 1068 303 249 606 882 573 124 304 320 1209 1078 1272 416 499 1164 494 117 1188 643 551 420 820 1130 771 928